Sorbentes de bajo costo y materiales reciclados para la remoción de contaminantes en agua
DOI:
https://doi.org/10.59741/agraria.v23i2.737Palabras clave:
Adsorción, Tratamiento de aguas, Residuos agroindustriales, Polímeros reciclados, Economía circularResumen
La contaminación del agua y la creciente escasez de agua potable exigen tecnologías de tratamiento eficientes y accesibles. Aunque la sorción es una opción eficaz, el alto costo de los materiales comerciales limita su uso a gran escala, especialmente en países en desarrollo. En este contexto, este trabajo explora la valorización de residuos agroindustriales y poliméricos como sorbentes de bajo costo. Se revisan los fundamentos del proceso, incluyendo mecanismos de fisisorción y quimisorción, así como modelos cinéticos e isotérmicos, y se destaca que, mediante modificaciones químicas y térmicas, estos materiales pueden alcanzar capacidades competitivas, superando en algunos casos los 400 mg/g para contaminantes como metales y colorantes. Desde una perspectiva de economía circular, esta estrategia es prometedora, aunque persisten desafíos en su escalado, regeneración y validación en condiciones reales.
Descargas
Referencias
Agboola, O.D. y Benson, N.U. (2021) ‘Physisorption and chemisorption mechanisms influencing micro (nano) plastics-organic chemical contaminants interactions: a review’, Frontiers in Environmental Science, 9. https://doi.org/10.3389/fenvs.2021.678574 DOI: https://doi.org/10.3389/fenvs.2021.678574
Al-Ghouti, M.A. y Da’ana, D.A. (2020) ‘Guidelines for the use and interpretation of adsorption isotherm models: a review’, Journal of Hazardous Materials, 393, 122383. https://doi.org/10.1016/j.jhazmat.2020.122383 DOI: https://doi.org/10.1016/j.jhazmat.2020.122383
Alkhaldi, H., Alharthi, S., Alharthi, S., AlGhamdi, H.A., AlZahrani, Y.M., Mahmoud, S.A., Amin, L.G., Al-Shaalan, N.H., Boraie, W.E., Attia, M.S., Al-Gahtany, S.A., Aldaleeli, N., Ghobashy, M.M., Sharshir, A.I., Madani, M., Darwesh, R. y Abaza, S.F. (2024) ‘Sustainable polymeric adsorbents for adsorption-based water remediation and pathogen deactivation: a review’. https://doi.org/10.1039/D4RA05269B DOI: https://doi.org/10.1039/D4RA05269B
Alwael, H., Alsulami, A.N., Abduljabbar, T.N., Oubaha, M. y El-Shahawi, M.S. (2024) ‘Innovative sol-gel functionalized polyurethane foam for sustainable water purification and analytical advances’, Frontiers in Chemistry, 12. https://doi.org/10.3389/fchem.2024.1324426 DOI: https://doi.org/10.3389/fchem.2024.1324426
Aprilita, N.H., Ofens, T.F.P., Nora, M., Nassir, T.A. y Wahyuni, E.T. (2024) ‘Conversion of styrofoam waste into a high-capacity and recoverable adsorbent for removing toxic Pb(II) from water media’, Global NEST Journal, pp. 1–10. https://doi.org/10.30955/gnj.005415 DOI: https://doi.org/10.30955/gnj.005415
Benítez, E.M.L., Verdecia, G.M. y Castell, M.A.P. (2021) ‘Escasez y contaminación del agua, realidades del siglo XXI’, Revista 16 de abril, 60(279), e854.
Cholico-González, D., Ortiz Lara, N., Fernández Macedo, A.M. y Chávez Salas, J. (2020) ‘Adsorption behavior of Pb(II), Cd(II), and Zn(II) onto agave bagasse: characterization and mechanism’, ACS Omega, 5(7), pp. 3302–3314. https://doi.org/10.1021/acsomega.9b03385 DOI: https://doi.org/10.1021/acsomega.9b03385
Crini, G., Lichtfouse, E., Wilson, L.D. y Morin-Crini, N. (2019) ‘Conventional and non-conventional adsorbents for wastewater treatment’, Environmental Chemistry Letters, 17(1), pp. 195–213. https://doi.org/10.1007/s10311-018-0786-8 DOI: https://doi.org/10.1007/s10311-018-0786-8
Cusioli, L.F., Mantovani, D., Bergamasco, R., Tusset, A.M. y Lenzi, G.G. (2023) ‘Preparation of a new adsorbent material from agro-industrial waste and comparison with commercial adsorbent for emerging contaminant removal’, Processes, 11(8), 2478. https://doi.org/10.3390/pr11082478 DOI: https://doi.org/10.3390/pr11082478
Duany-Timosthe, S., Arias-Lafargue, T., Bessy-Horruitiner, T. y Rodríguez-Heredia, D. (2022) ‘Bioadsorbentes no convencionales empleados en la remoción de metales pesados. Revisión’, Tecnología Química, 42(1), pp. 94–113.
Escamilla-Lara, K.A., López-Téllez, J. y Rodríguez, J.A. (2023) ‘Adsorbents obtained from recycled polymeric materials for retention of different pollutants: a review’, Chemosphere, 335, 139159. https://doi.org/10.1016/j.chemosphere.2023.139159 DOI: https://doi.org/10.1016/j.chemosphere.2023.139159
Flórez, E.C. y Marulanda, L.F. (2020) ‘Uso de residuos de café como biosorbente para la remoción de metales pesados en aguas residuales’, Ingenierías USBMed, 11(1), pp. 44–55. https://doi.org/10.21500/20275846.4477 DOI: https://doi.org/10.21500/20275846.4477
Georgin, J., Meili, L. y Franco, D. (2023) ‘A review of the application of low-cost adsorbents as an alternative method for biosorption of contaminants present in water’, Latin American Developments in Energy Engineering, 4(2), pp. 1–20. https://doi.org/10.17981/ladee.04.02.2023.1 DOI: https://doi.org/10.17981/ladee.04.02.2023.1
Giraldo, S., Acelas, N.Y., Ocampo-Pérez, R., Padilla-Ortega, E., Flórez, E., Franco, C.A., Cortés, F.B. y Forgionny, A. (2022) ‘Application of orange peel waste as adsorbent for methylene blue and Cd2+ simultaneous remediation’, Molecules, 27(16), 5105. https://doi.org/10.3390/molecules27165105 DOI: https://doi.org/10.3390/molecules27165105
He, M., Zhang, P., Huo, S., Zhang, X., Gong, A., Zhang, W. y Li, K. (2022) ‘Remarkable phosphate electrosorption/desorption by bimetallic MOF-derived hierarchically porous carbon electrode’, Chemical Engineering Journal, 446, 137396. https://doi.org/10.1016/j.cej.2022.137396 DOI: https://doi.org/10.1016/j.cej.2022.137396
Hou, C., Zhang, Y., Liao, Q. y Chen, Q. (2024) ‘Ultra-cheap and ultra-stable adsorption materials based on nylon and removal performance of copper ion’, Separation and Purification Technology, 336, 126346. https://doi.org/10.1016/j.seppur.2024.126346 DOI: https://doi.org/10.1016/j.seppur.2024.126346
Hu, Q., Lan, R., He, L., Liu, H. y Pei, X. (2023) ‘A critical review of adsorption isotherm models for aqueous contaminants’, Journal of Environmental Management, 329, 117104. https://doi.org/10.1016/j.jenvman.2022.117104 DOI: https://doi.org/10.1016/j.jenvman.2022.117104
Jing, L., Shi, T., Chang, Y., Meng, X., He, S., Xu, H., Yang, S. y Liu, J. (2024) ‘Cellulose-based materials in environmental protection: a scientometric and visual analysis review’, Science of the Total Environment, 929, 172576. https://doi.org/10.1016/j.scitotenv.2024.172576 DOI: https://doi.org/10.1016/j.scitotenv.2024.172576
Kataya, G., Issa, M., Jeguirim, M. y Hijazi, A. (2023) ‘Characterization and environmental application potential of banana peels biochar’, Engineering Proceedings, 37(1), 105. https://doi.org/10.3390/ECP2023-14725 DOI: https://doi.org/10.3390/ECP2023-14725
Khakbaz, M., Ghaemi, A. y Mir Mohamad Sadeghi, G. (2023) ‘Evaluation of hypercrosslinked waste polycarbonate for the removal of lead ions from aqueous solutions’, Polymer Bulletin. https://doi.org/10.1007/s00289-023-04813-6 DOI: https://doi.org/10.1007/s00289-023-04813-6
Liu, Y., Biswas, B., Hassan, M. y Naidu, R. (2024) ‘Green adsorbents for environmental remediation: synthesis methods, ecotoxicity, and reusability prospects’, Processes, 12(6), 1195. https://doi.org/10.3390/pr12061195 DOI: https://doi.org/10.3390/pr12061195
Lu, H., et al., 2023. ‘Effect of ultrasound-assisted EDTA and citric acid washing on heavy metal removal, residual heavy metal mobility, and sewage sludge quality’. Water Science and Technology, 88(6), 1594–1607. https://doi.org/10.2166/wst.2023.289 DOI: https://doi.org/10.2166/wst.2023.289
Madeła, M. y Skuza, M. (2021) ‘Towards a circular economy: analysis of the use of biowaste as biosorbent for the removal of heavy metals’, Energies, 14(17), 5427. https://doi.org/10.3390/en14175427 DOI: https://doi.org/10.3390/en14175427
Martínez-Alcalá, I., Soto, J. y Lahora, A. (2020) ‘Antibióticos como contaminantes emergentes’, Ecosistemas, 29(3), 2070. https://doi.org/10.7818/ECOS.2070 DOI: https://doi.org/10.7818/ECOS.2070
Musah, M., Azeh, Y., Mathew, J., Umar, M., Abdulhamid, Z. y Muhammad, A. (2022) ‘Adsorption kinetics and isotherm models: a review’, Caliphate Journal of Science and Technology, 4(1), pp. 20–26. https://doi.org/10.4314/cajost.v4i1.3 DOI: https://doi.org/10.4314/cajost.v4i1.3
Olawade, D.B., Wada, O.Z., Egbewole, B.I., Fapohunda, O., Ige, A.O., Usman, S.O. y Ajisafe, O. (2024) ‘Metal and metal oxide nanomaterials for heavy metal remediation’, Frontiers in Nanotechnology, 6. https://doi.org/10.3389/fnano.2024.1466721 DOI: https://doi.org/10.3389/fnano.2024.1466721
Pereira, L., Martín-Lara, M.Á., Garcia-Garcia, G., Calvo, C., Robledo, T., Solís, R.R. y Calero, M. (2025) ‘Plastic waste to carbon adsorbent: activation with sodium carbonate and functionalization with citric acid’, Applied Sciences, 15(3), 1634. https://doi.org/10.3390/app15031634 DOI: https://doi.org/10.3390/app15031634
Pham, T. (2023) ‘Synthesis of activated carbon from polyethylene terephthalate (PET) plastic waste’, Non-Metallic Material Science, 5. https://doi.org/10.30564/nmms.v5i1.5663 DOI: https://doi.org/10.30564/nmms.v5i1.5663
Robledo-Peralta, A., García-Quiñonez, L.V., Rodríguez-Beltrán, R.I. y Reynoso-Cuevas, L. (2022) ‘Zr-based biocomposite materials as an alternative for fluoride removal’, Polymers, 14(8), 1575. https://doi.org/10.3390/polym14081575 DOI: https://doi.org/10.3390/polym14081575
Ungureanu, E.L., Mocanu, A.L., Stroe, C.A., Panciu, C.M., Berca, L., Sionel, R.M. y Mustatea, G. (2023) ‘Agricultural byproducts used as low-cost adsorbents’, Sustainability, 15(7), 5999. https://doi.org/10.3390/su15075999 DOI: https://doi.org/10.3390/su15075999
Wang, J. y Guo, X. (2020) ‘Adsorption kinetic models: physical meanings, applications, and solving methods’, Journal of Hazardous Materials, 390, 122156. https://doi.org/10.1016/j.jhazmat.2020.122156 DOI: https://doi.org/10.1016/j.jhazmat.2020.122156
Wang, X., Xu, Y., Ou, Q., Chen, W., van der Meer, W. y Liu, G. (2024) ‘Adsorption characteristics and mechanisms of water-soluble polymers on minerals’, Journal of Hazardous Materials, 466, 133592. https://doi.org/10.1016/j.jhazmat.2024.133592 DOI: https://doi.org/10.1016/j.jhazmat.2024.133592
Yang, W., Schmidt, C., Wu, S., Zhao, Z., Li, R., Wang, Z., Wang, H., Hua, P., Krebs, P. y Zhang, J. (2025) ‘Exacerbated anthropogenic water pollution under climate change and urbanization’, Water Research, 280, 123449. https://doi.org/10.1016/j.watres.2025.123449 DOI: https://doi.org/10.1016/j.watres.2025.123449
Zaimee, M.Z.A., Sarjadi, M.S. y Rahman, M.L. (2021) ‘Heavy metals removal from water by efficient adsorbents’, Water, 13(19), 2659. https://doi.org/10.3390/w13192659 DOI: https://doi.org/10.3390/w13192659
Zaritzky, N.E., Choren, H., Paladino, J.J., Nudelman, N.S. y Flores, M.M. (2024) Tecnologías de reciclado y valorización de residuos plásticos.
Descargas
Publicado
Número
Sección
Licencia
Derechos de autor 2026 Universidad Autónoma Agraria Antonio Narro

Esta obra está bajo una licencia internacional Creative Commons Atribución-CompartirIgual 4.0.
Cómo citar
PLUMX Metrics